A rhenium-catalyzed N-selective allylic amination reaction of N-hydroxycarbamates has been developed. This reaction occurs with excellent N/O selectivity and with complete carbon selectivity on the allylic system. The reaction is tolerant of many functional groups and also proceeds with N-hydroxysulfonamides and hydroxamic acids.
|Number of pages||7|
|Journal||Journal of Organic Chemistry|
|Early online date||03 Nov 2014|
|Publication status||Published - 2014|