Silicon-Directed Rhenium-Catalyzed Allylic Substitutions with N‑Hydroxycarbamates, N‑Hydroxysulfonamides, and Hydroxamic Acids

Sanjay W. Chavhan, Catherine A. McAdam, Matthew J. Cook

Research output: Contribution to journalArticlepeer-review

13 Citations (Scopus)

Abstract

A rhenium-catalyzed N-selective allylic amination reaction of N-hydroxycarbamates has been developed. This reaction occurs with excellent N/O selectivity and with complete carbon selectivity on the allylic system. The reaction is tolerant of many functional groups and also proceeds with N-hydroxysulfonamides and hydroxamic acids.
Original languageEnglish
Pages (from-to)11234−11240
Number of pages7
JournalJournal of Organic Chemistry
Volume79
Issue number22
Early online date03 Nov 2014
DOIs
Publication statusPublished - 2014

Fingerprint

Dive into the research topics of 'Silicon-Directed Rhenium-Catalyzed Allylic Substitutions with N‑Hydroxycarbamates, N‑Hydroxysulfonamides, and Hydroxamic Acids'. Together they form a unique fingerprint.

Cite this