Abstract
A rhenium-catalyzed N-selective allylic amination reaction of N-hydroxycarbamates has been developed. This reaction occurs with excellent N/O selectivity and with complete carbon selectivity on the allylic system. The reaction is tolerant of many functional groups and also proceeds with N-hydroxysulfonamides and hydroxamic acids.
Original language | English |
---|---|
Pages (from-to) | 11234−11240 |
Number of pages | 7 |
Journal | Journal of Organic Chemistry |
Volume | 79 |
Issue number | 22 |
Early online date | 03 Nov 2014 |
DOIs | |
Publication status | Published - 2014 |