Small-angle scattering from long-chain alkylimidazolium-based ionic liquids

Christopher Hardacre, John Holbrey, S.E.J. McMath, Mark Nieuwenhuyzen

Research output: Chapter in Book/Report/Conference proceedingChapter (peer-reviewed)

16 Citations (Scopus)

Abstract

This paper compares the structure of 1-alkyl-3-methylim ridazolium salts using SAXS and X-ray reflectivity. A range of anions have been investigated namely chloride, bromide, trifluoromethanesulfonate (OTf), bis(trifluoromethanesulfonyl)imide (TFI) and tetrachloropalladate(II) with cation alkyl chains ranging from n = 12-20. In general, the salts show liquid crystalline behaviour whose structure is still observed on melting into an isotropic liquid.
Original languageEnglish
Title of host publicationonic Liquids: Industrial Applications for Green Chemistry
EditorsKenneth Seddon, Robin Rogers
PublisherAmerican Chemical Society
Pages400-412
Number of pages13
Volume818
Publication statusPublished - 2002

Publication series

NameACS Symposium Series
PublisherAmerican Chemical Society
Volume818

Fingerprint

Ionic Liquids
Salts
Scattering
Liquids
Bromides
Anions
Cations
Chlorides
Melting
Crystalline materials
X rays
tetrachloropalladium
trifluoromethanesulfonic acid
bis(trifluoromethanesulfonyl)imide

Cite this

Hardacre, C., Holbrey, J., McMath, S. E. J., & Nieuwenhuyzen, M. (2002). Small-angle scattering from long-chain alkylimidazolium-based ionic liquids. In K. Seddon, & R. Rogers (Eds.), onic Liquids: Industrial Applications for Green Chemistry (Vol. 818, pp. 400-412). (ACS Symposium Series; Vol. 818). American Chemical Society.
Hardacre, Christopher ; Holbrey, John ; McMath, S.E.J. ; Nieuwenhuyzen, Mark. / Small-angle scattering from long-chain alkylimidazolium-based ionic liquids. onic Liquids: Industrial Applications for Green Chemistry. editor / Kenneth Seddon ; Robin Rogers. Vol. 818 American Chemical Society, 2002. pp. 400-412 (ACS Symposium Series).
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Hardacre, C, Holbrey, J, McMath, SEJ & Nieuwenhuyzen, M 2002, Small-angle scattering from long-chain alkylimidazolium-based ionic liquids. in K Seddon & R Rogers (eds), onic Liquids: Industrial Applications for Green Chemistry. vol. 818, ACS Symposium Series, vol. 818, American Chemical Society, pp. 400-412.

Small-angle scattering from long-chain alkylimidazolium-based ionic liquids. / Hardacre, Christopher; Holbrey, John; McMath, S.E.J.; Nieuwenhuyzen, Mark.

onic Liquids: Industrial Applications for Green Chemistry. ed. / Kenneth Seddon; Robin Rogers. Vol. 818 American Chemical Society, 2002. p. 400-412 (ACS Symposium Series; Vol. 818).

Research output: Chapter in Book/Report/Conference proceedingChapter (peer-reviewed)

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N2 - This paper compares the structure of 1-alkyl-3-methylim ridazolium salts using SAXS and X-ray reflectivity. A range of anions have been investigated namely chloride, bromide, trifluoromethanesulfonate (OTf), bis(trifluoromethanesulfonyl)imide (TFI) and tetrachloropalladate(II) with cation alkyl chains ranging from n = 12-20. In general, the salts show liquid crystalline behaviour whose structure is still observed on melting into an isotropic liquid.

AB - This paper compares the structure of 1-alkyl-3-methylim ridazolium salts using SAXS and X-ray reflectivity. A range of anions have been investigated namely chloride, bromide, trifluoromethanesulfonate (OTf), bis(trifluoromethanesulfonyl)imide (TFI) and tetrachloropalladate(II) with cation alkyl chains ranging from n = 12-20. In general, the salts show liquid crystalline behaviour whose structure is still observed on melting into an isotropic liquid.

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M3 - Chapter (peer-reviewed)

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T3 - ACS Symposium Series

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BT - onic Liquids: Industrial Applications for Green Chemistry

A2 - Seddon, Kenneth

A2 - Rogers, Robin

PB - American Chemical Society

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Hardacre C, Holbrey J, McMath SEJ, Nieuwenhuyzen M. Small-angle scattering from long-chain alkylimidazolium-based ionic liquids. In Seddon K, Rogers R, editors, onic Liquids: Industrial Applications for Green Chemistry. Vol. 818. American Chemical Society. 2002. p. 400-412. (ACS Symposium Series).