Solid–liquid equilibria in systems [Cxmim][Tf2N] with diethylamine

Jan Rotrekl, Pavel Vrbka, Zuzana Sedláková, Zdeněk Wagner, Johan Jacquemin, Magdalena Bendová

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

In the present work, the solid–liquid–liquid equilibrium in the binary system of diethylamine (1) and ionic liquid (2) 1-methyl-3-ethylimidazolium bis(trifluoromethylsulfonyl)imide and solid–liquid equilibrium in system 1-methyl-3-butylimidazolium bis(trifluoromethylsulfonyl)imide was studied. Phase equilibrium was determined experimentally by means of a polythermic method. These data were then used to determine the activity coefficients for both ionic liquids. For the pure diethylamine the enthalpy of fusion was determined by differential scanning calorimetry, because to the best of our knowledge, this data is not yet reported in the open literature, a contrario of pure ionic liquids tested during this work.
Original languageEnglish
Pages (from-to)453–460
Number of pages7
JournalPure and Applied Chemistry
Volume87
Issue number5
Early online date07 Mar 2015
DOIs
Publication statusPublished - May 2015

Bibliographical note

M1 - 5

Keywords

  • calorimetry
  • ionic liquids
  • ISSP-16
  • solubility

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