Stability and thermal decomposition of quaternary and protonated imidazolium nitrate and picrate salts

J. D. Holbrey; W. M. Reichert; M. Smiglak; S. K. Spear; H. Yang; K. Manju; K. Kirichenko; A. R. Katritzky; J. S. Thrasher; L. Y. Sun; R. D. Rogers

Stability and thermal decomposition of quaternary and protonated imidazolium nitrate and picrate salts

J. D. Holbrey^*, W. M. Reichert, M. Smiglak, S. K. Spear, H. Yang, K. Manju, K. Kirichenko, A. R. Katritzky, J. S. Thrasher, L. Y. Sun, R. D. Rogers

^*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

3 Citations (Scopus)

Abstract

The stability, liquid ranges, and thermal decomposition of a series of quaternized and protonated imidazolium nitrate and picrate salts have been investigated. The quaternized, N,N'-dialkylated imidazolium salts are more stable than the protonated examples, and salts with picrate anions are surprisingly more stable than the corresponding nitrate salts and in each case, decompose exothermically yielding volatile decomposition products.

Original language	English
Title of host publication	Molten Salts XIV - Proceedings of the International Symposium
Pages	396-406
Number of pages	11
Volume	PV 2004-24
Publication status	Published - 01 Dec 2006
Externally published	Yes
Event	206th Electrochemical Society Meeting - Honolulu, United States Duration: 03 Oct 2004 → 08 Oct 2004 https://www.electrochem.org/206

Conference

Conference	206th Electrochemical Society Meeting
Abbreviated title	ECS
Country/Territory	United States
City	Honolulu
Period	03/10/2004 → 08/10/2004
Internet address	https://www.electrochem.org/206

ASJC Scopus subject areas

General Engineering

Cite this

@inproceedings{b0df57ce5e504e20b1b53df615911efd,

title = "Stability and thermal decomposition of quaternary and protonated imidazolium nitrate and picrate salts",

abstract = "The stability, liquid ranges, and thermal decomposition of a series of quaternized and protonated imidazolium nitrate and picrate salts have been investigated. The quaternized, N,N'-dialkylated imidazolium salts are more stable than the protonated examples, and salts with picrate anions are surprisingly more stable than the corresponding nitrate salts and in each case, decompose exothermically yielding volatile decomposition products.",

author = "Holbrey, {J. D.} and Reichert, {W. M.} and M. Smiglak and Spear, {S. K.} and H. Yang and K. Manju and K. Kirichenko and Katritzky, {A. R.} and Thrasher, {J. S.} and Sun, {L. Y.} and Rogers, {R. D.}",

year = "2006",

month = dec,

day = "1",

language = "English",

isbn = "9781566775144",

volume = "PV 2004-24",

pages = "396--406",

booktitle = "Molten Salts XIV - Proceedings of the International Symposium",

note = "206th Electrochemical Society Meeting, ECS ; Conference date: 03-10-2004 Through 08-10-2004",

url = "https://www.electrochem.org/206",

}

Holbrey, JD, Reichert, WM, Smiglak, M, Spear, SK, Yang, H, Manju, K, Kirichenko, K, Katritzky, AR, Thrasher, JS, Sun, LY & Rogers, RD 2006, Stability and thermal decomposition of quaternary and protonated imidazolium nitrate and picrate salts. in Molten Salts XIV - Proceedings of the International Symposium. vol. PV 2004-24, pp. 396-406, 206th Electrochemical Society Meeting, Honolulu, Hawaii, United States, 03/10/2004.

TY - GEN

T1 - Stability and thermal decomposition of quaternary and protonated imidazolium nitrate and picrate salts

AU - Holbrey, J. D.

AU - Reichert, W. M.

AU - Smiglak, M.

AU - Spear, S. K.

AU - Yang, H.

AU - Manju, K.

AU - Kirichenko, K.

AU - Katritzky, A. R.

AU - Thrasher, J. S.

AU - Sun, L. Y.

AU - Rogers, R. D.

PY - 2006/12/1

Y1 - 2006/12/1

N2 - The stability, liquid ranges, and thermal decomposition of a series of quaternized and protonated imidazolium nitrate and picrate salts have been investigated. The quaternized, N,N'-dialkylated imidazolium salts are more stable than the protonated examples, and salts with picrate anions are surprisingly more stable than the corresponding nitrate salts and in each case, decompose exothermically yielding volatile decomposition products.

AB - The stability, liquid ranges, and thermal decomposition of a series of quaternized and protonated imidazolium nitrate and picrate salts have been investigated. The quaternized, N,N'-dialkylated imidazolium salts are more stable than the protonated examples, and salts with picrate anions are surprisingly more stable than the corresponding nitrate salts and in each case, decompose exothermically yielding volatile decomposition products.

UR - http://www.scopus.com/inward/record.url?scp=37349021037&partnerID=8YFLogxK

M3 - Conference contribution

AN - SCOPUS:37349021037

SN - 9781566775144

VL - PV 2004-24

SP - 396

EP - 406

BT - Molten Salts XIV - Proceedings of the International Symposium

T2 - 206th Electrochemical Society Meeting

Y2 - 3 October 2004 through 8 October 2004

ER -

Stability and thermal decomposition of quaternary and protonated imidazolium nitrate and picrate salts

Abstract

Conference

ASJC Scopus subject areas

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