Sulfated zirconia in SBA-15 structures with strong Bronsted acidity as observed by H-1 MAS NMR spectroscopy

Volkan Degirmenci; Ozlen Ferruh Erdem; Aysen Yilmaz; Dieter Michel; Deniz Uner

doi:10.1007/s10562-007-9078-9

Sulfated zirconia in SBA-15 structures with strong Bronsted acidity as observed by H-1 MAS NMR spectroscopy

Volkan Degirmenci
, Ozlen Ferruh Erdem
, Aysen Yilmaz
, Dieter Michel
, Deniz Uner

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

In order to prepare high surface area highly acidic catalysts, different weight loadings of ZrO2 were incorporated in the SBA-15 structures which are subsequently sulfated by treating in 0.25 M H2SO4. The catalysts were characterized by means of TEM, XRD, N-2 adsorption, and H-1 MAS NMR. Bronsted type acidities of sulfated zirconia included SBA-15 materials were identified by a sharp H-1 MAS NMR line at 10.6 ppm. The highest acidity was obtained in the 25 mol% ZrO2 included SBA-15 catalyst with a BET surface area of 246 m(2)/g.

Original language	English
Pages (from-to)	79-85
Number of pages	7
Journal	Catalysis Letters
Volume	115
Issue number	1-2
DOIs	https://doi.org/10.1007/s10562-007-9078-9
Publication status	Published - May 2007

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Catalysis

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10.1007/s10562-007-9078-9

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title = "Sulfated zirconia in SBA-15 structures with strong Bronsted acidity as observed by H-1 MAS NMR spectroscopy",

abstract = "In order to prepare high surface area highly acidic catalysts, different weight loadings of ZrO2 were incorporated in the SBA-15 structures which are subsequently sulfated by treating in 0.25 M H2SO4. The catalysts were characterized by means of TEM, XRD, N-2 adsorption, and H-1 MAS NMR. Bronsted type acidities of sulfated zirconia included SBA-15 materials were identified by a sharp H-1 MAS NMR line at 10.6 ppm. The highest acidity was obtained in the 25 mol\% ZrO2 included SBA-15 catalyst with a BET surface area of 246 m(2)/g.",

author = "Volkan Degirmenci and Erdem, \{Ozlen Ferruh\} and Aysen Yilmaz and Dieter Michel and Deniz Uner",

year = "2007",

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doi = "10.1007/s10562-007-9078-9",

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journal = "Catalysis Letters",

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T1 - Sulfated zirconia in SBA-15 structures with strong Bronsted acidity as observed by H-1 MAS NMR spectroscopy

AU - Degirmenci, Volkan

AU - Erdem, Ozlen Ferruh

AU - Yilmaz, Aysen

AU - Michel, Dieter

AU - Uner, Deniz

PY - 2007/5

Y1 - 2007/5

N2 - In order to prepare high surface area highly acidic catalysts, different weight loadings of ZrO2 were incorporated in the SBA-15 structures which are subsequently sulfated by treating in 0.25 M H2SO4. The catalysts were characterized by means of TEM, XRD, N-2 adsorption, and H-1 MAS NMR. Bronsted type acidities of sulfated zirconia included SBA-15 materials were identified by a sharp H-1 MAS NMR line at 10.6 ppm. The highest acidity was obtained in the 25 mol% ZrO2 included SBA-15 catalyst with a BET surface area of 246 m(2)/g.

AB - In order to prepare high surface area highly acidic catalysts, different weight loadings of ZrO2 were incorporated in the SBA-15 structures which are subsequently sulfated by treating in 0.25 M H2SO4. The catalysts were characterized by means of TEM, XRD, N-2 adsorption, and H-1 MAS NMR. Bronsted type acidities of sulfated zirconia included SBA-15 materials were identified by a sharp H-1 MAS NMR line at 10.6 ppm. The highest acidity was obtained in the 25 mol% ZrO2 included SBA-15 catalyst with a BET surface area of 246 m(2)/g.

U2 - 10.1007/s10562-007-9078-9

DO - 10.1007/s10562-007-9078-9

M3 - Article

SN - 1011-372X

VL - 115

SP - 79

EP - 85

JO - Catalysis Letters

JF - Catalysis Letters

IS - 1-2

ER -

Sulfated zirconia in SBA-15 structures with strong Bronsted acidity as observed by H-1 MAS NMR spectroscopy

Abstract

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