Sustainable cyclic carbonate production, utilising carbon dioxide and azolate ionic liquids

Peter Goodrich; H. Q. Nimal Gunaratne; Johan Jacquemin; Lili Jin; Yuntao Lei; Kenneth R. Seddon

doi:10.1021/acssuschemeng.7b00355

Sustainable cyclic carbonate production, utilising carbon dioxide and azolate ionic liquids

Peter Goodrich, H. Q. Nimal Gunaratne, Johan Jacquemin, Lili Jin, Yuntao Lei, Kenneth R. Seddon

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Abstract

An efficient protocol is described for producing cyclic carbonates in good to excellent yields under moderate reaction conditions (100.0 °C, 1.0 MPa) by treating epoxides with carbon dioxide, promoted by a series of azolate ionic liquids, which are effective recyclable metal-free and halide-free catalysts.

Original language	English
Pages (from-to)	5635
Journal	ACS Sustainable Chemistry & Engineering
Volume	5
Issue number	7
Early online date	06 Jun 2017
DOIs	https://doi.org/10.1021/acssuschemeng.7b00355
Publication status	Early online date - 06 Jun 2017

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Sustainable cyclic carbonate production, utilising carbon dioxide and azolate ionic liquids
© 2017 American Chemical Society. This work is made available online in accordance with the publisher’s policies. Please refer to any applicable terms of use of the publisher.
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AU - Lei, Yuntao

AU - Seddon, Kenneth R.

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AB - An efficient protocol is described for producing cyclic carbonates in good to excellent yields under moderate reaction conditions (100.0 °C, 1.0 MPa) by treating epoxides with carbon dioxide, promoted by a series of azolate ionic liquids, which are effective recyclable metal-free and halide-free catalysts.

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Sustainable cyclic carbonate production, utilising carbon dioxide and azolate ionic liquids

Abstract

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