Sustainable cyclic carbonate production, utilising carbon dioxide and azolate ionic liquids

Peter Goodrich; H. Q. Nimal Gunaratne; Johan Jacquemin; Lili Jin; Yuntao Lei; Kenneth R. Seddon

doi:10.1021/acssuschemeng.7b00355

Sustainable cyclic carbonate production, utilising carbon dioxide and azolate ionic liquids

Peter Goodrich
, H. Q. Nimal Gunaratne
, Johan Jacquemin
, Lili Jin
, Yuntao Lei
, Kenneth R. Seddon

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

105 Citations (Scopus)

914 Downloads (Pure)

Abstract

An efficient protocol is described for producing cyclic carbonates in good to excellent yields under moderate reaction conditions (100.0 °C, 1.0 MPa) by treating epoxides with carbon dioxide, promoted by a series of azolate ionic liquids, which are effective recyclable metal-free and halide-free catalysts.

Original language	English
Pages (from-to)	5635
Journal	ACS Sustainable Chemistry & Engineering
Volume	5
Issue number	7
Early online date	06 Jun 2017
DOIs	https://doi.org/10.1021/acssuschemeng.7b00355
Publication status	Early online date - 06 Jun 2017

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Sustainable cyclic carbonate production, utilising carbon dioxide and azolate ionic liquids
© 2017 American Chemical Society. This work is made available online in accordance with the publisher’s policies. Please refer to any applicable terms of use of the publisher.
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Nimal Gunaratne
- n.gunaratnequb.acuk
- School of Chemistry and Chemical Engineering - Honorary Senior Lecturer
Person: Honorary

Cite this

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title = "Sustainable cyclic carbonate production, utilising carbon dioxide and azolate ionic liquids",

abstract = "An efficient protocol is described for producing cyclic carbonates in good to excellent yields under moderate reaction conditions (100.0 °C, 1.0 MPa) by treating epoxides with carbon dioxide, promoted by a series of azolate ionic liquids, which are effective recyclable metal-free and halide-free catalysts.",

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AU - Goodrich, Peter

AU - Gunaratne, H. Q. Nimal

AU - Jacquemin, Johan

AU - Jin, Lili

AU - Lei, Yuntao

AU - Seddon, Kenneth R.

PY - 2017/6/6

Y1 - 2017/6/6

N2 - An efficient protocol is described for producing cyclic carbonates in good to excellent yields under moderate reaction conditions (100.0 °C, 1.0 MPa) by treating epoxides with carbon dioxide, promoted by a series of azolate ionic liquids, which are effective recyclable metal-free and halide-free catalysts.

AB - An efficient protocol is described for producing cyclic carbonates in good to excellent yields under moderate reaction conditions (100.0 °C, 1.0 MPa) by treating epoxides with carbon dioxide, promoted by a series of azolate ionic liquids, which are effective recyclable metal-free and halide-free catalysts.

U2 - 10.1021/acssuschemeng.7b00355

DO - 10.1021/acssuschemeng.7b00355

M3 - Article

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Sustainable cyclic carbonate production, utilising carbon dioxide and azolate ionic liquids

Abstract

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Nimal Gunaratne

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