Synthesis and potential applications of cyclodextrin-based metal–organic frameworks: a review

Yang  Xu; Ahmed K.  Rashwan; Ahmed I. Osman; Eman M.  Abd El-Monaem; Ahmed M. Elgarahy; Abdelazeem S.  Eltaweil; Mirna  Omar; Yuting Li; Abul-Hamd E.  Mehanni; Wei  Chen; David W. Rooney

doi:10.1007/s10311-022-01509-7

Synthesis and potential applications of cyclodextrin-based metal–organic frameworks: a review

Yang Xu, Ahmed K. Rashwan, Ahmed I. Osman^*, Eman M. Abd El-Monaem, Ahmed M. Elgarahy, Abdelazeem S. Eltaweil, Mirna Omar, Yuting Li^*, Abul-Hamd E. Mehanni, Wei Chen^*, David W. Rooney

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Review article › peer-review

66 Citations (Scopus)

327 Downloads (Pure)

Abstract

Metal–organic frameworks are porous polymeric materials formed by linking metal ions with organic bridging ligands. Metal–organic frameworks are used as sensors, catalysts for organic transformations, biomass conversion, photovoltaics, electrochemical applications, gas storage and separation, and photocatalysis. Nonetheless, many actual metal–organic frameworks present limitations such as toxicity of preparation reagents and components, which make frameworks unusable for food and pharmaceutical applications. Here, we review the structure, synthesis and properties of cyclodextrin-based metal–organic frameworks that could be used in bioapplications. Synthetic methods include vapor diffusion, microwave-assisted, hydro/solvothermal, and ultrasound techniques. The vapor diffusion method can produce cyclodextrin-based metal–organic framework crystals with particle sizes ranging from 200 nm to 400 μm. Applications comprise food packaging, drug delivery, sensors, adsorbents, gas separation, and membranes. Cyclodextrin-based metal–organic frameworks showed loading efficacy of the bioactive compounds ranging from 3.29 to 97.80%.

Original language	English
Number of pages	31
Journal	Environmental Chemistry Letters
Early online date	19 Sept 2022
DOIs	https://doi.org/10.1007/s10311-022-01509-7
Publication status	Early online date - 19 Sept 2022

Keywords

Metal–organic frameworks
Cyclodextrin
Synthesis methods
Cyclodextrin-based metal–organic framework applications
bioengineering
MOFs
adsorption
Food application
drug delivery
Circular bioeconomy

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Synthesis and potential applications of cyclodextrin-based metal–organic frameworks: a review
Copyright 2022 The Authors. This is an open access article published under a Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited.
Final published version, 2.77 MBLicence: CC BY

Cite this

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title = "Synthesis and potential applications of cyclodextrin-based metal–organic frameworks: a review",

abstract = "Metal–organic frameworks are porous polymeric materials formed by linking metal ions with organic bridging ligands. Metal–organic frameworks are used as sensors, catalysts for organic transformations, biomass conversion, photovoltaics, electrochemical applications, gas storage and separation, and photocatalysis. Nonetheless, many actual metal–organic frameworks present limitations such as toxicity of preparation reagents and components, which make frameworks unusable for food and pharmaceutical applications. Here, we review the structure, synthesis and properties of cyclodextrin-based metal–organic frameworks that could be used in bioapplications. Synthetic methods include vapor diffusion, microwave-assisted, hydro/solvothermal, and ultrasound techniques. The vapor diffusion method can produce cyclodextrin-based metal–organic framework crystals with particle sizes ranging from 200 nm to 400 μm. Applications comprise food packaging, drug delivery, sensors, adsorbents, gas separation, and membranes. Cyclodextrin-based metal–organic frameworks showed loading efficacy of the bioactive compounds ranging from 3.29 to 97.80%.",

keywords = "Metal–organic frameworks, Cyclodextrin, Synthesis methods, Cyclodextrin-based metal–organic framework applications, bioengineering, MOFs, adsorption, Food application, drug delivery, Circular bioeconomy",

author = "Yang Xu and Rashwan, {Ahmed K.} and Osman, {Ahmed I.} and {Abd El-Monaem}, {Eman M.} and Elgarahy, {Ahmed M.} and Eltaweil, {Abdelazeem S.} and Mirna Omar and Yuting Li and Mehanni, {Abul-Hamd E.} and Wei Chen and Rooney, {David W.}",

year = "2022",

month = sep,

day = "19",

doi = "10.1007/s10311-022-01509-7",

language = "English",

journal = "Environmental Chemistry Letters",

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T1 - Synthesis and potential applications of cyclodextrin-based metal–organic frameworks: a review

AU - Xu, Yang

AU - Rashwan, Ahmed K.

AU - Osman, Ahmed I.

AU - Abd El-Monaem, Eman M.

AU - Elgarahy, Ahmed M.

AU - Eltaweil, Abdelazeem S.

AU - Omar, Mirna

AU - Li, Yuting

AU - Mehanni, Abul-Hamd E.

AU - Chen, Wei

AU - Rooney, David W.

PY - 2022/9/19

Y1 - 2022/9/19

N2 - Metal–organic frameworks are porous polymeric materials formed by linking metal ions with organic bridging ligands. Metal–organic frameworks are used as sensors, catalysts for organic transformations, biomass conversion, photovoltaics, electrochemical applications, gas storage and separation, and photocatalysis. Nonetheless, many actual metal–organic frameworks present limitations such as toxicity of preparation reagents and components, which make frameworks unusable for food and pharmaceutical applications. Here, we review the structure, synthesis and properties of cyclodextrin-based metal–organic frameworks that could be used in bioapplications. Synthetic methods include vapor diffusion, microwave-assisted, hydro/solvothermal, and ultrasound techniques. The vapor diffusion method can produce cyclodextrin-based metal–organic framework crystals with particle sizes ranging from 200 nm to 400 μm. Applications comprise food packaging, drug delivery, sensors, adsorbents, gas separation, and membranes. Cyclodextrin-based metal–organic frameworks showed loading efficacy of the bioactive compounds ranging from 3.29 to 97.80%.

AB - Metal–organic frameworks are porous polymeric materials formed by linking metal ions with organic bridging ligands. Metal–organic frameworks are used as sensors, catalysts for organic transformations, biomass conversion, photovoltaics, electrochemical applications, gas storage and separation, and photocatalysis. Nonetheless, many actual metal–organic frameworks present limitations such as toxicity of preparation reagents and components, which make frameworks unusable for food and pharmaceutical applications. Here, we review the structure, synthesis and properties of cyclodextrin-based metal–organic frameworks that could be used in bioapplications. Synthetic methods include vapor diffusion, microwave-assisted, hydro/solvothermal, and ultrasound techniques. The vapor diffusion method can produce cyclodextrin-based metal–organic framework crystals with particle sizes ranging from 200 nm to 400 μm. Applications comprise food packaging, drug delivery, sensors, adsorbents, gas separation, and membranes. Cyclodextrin-based metal–organic frameworks showed loading efficacy of the bioactive compounds ranging from 3.29 to 97.80%.

KW - Metal–organic frameworks

KW - Cyclodextrin

KW - Synthesis methods

KW - Cyclodextrin-based metal–organic framework applications

KW - bioengineering

KW - MOFs

KW - adsorption

KW - Food application

KW - drug delivery

KW - Circular bioeconomy

U2 - 10.1007/s10311-022-01509-7

DO - 10.1007/s10311-022-01509-7

M3 - Review article

SN - 1610-3653

JO - Environmental Chemistry Letters

JF - Environmental Chemistry Letters

ER -

Synthesis and potential applications of cyclodextrin-based metal–organic frameworks: a review

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Keywords

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