Synthesis of a tri(organoplatinum) complex via the double directed lithiation of a mono(organoplatinum) precursor

Stuart James, N. Veldman, A.L. Spek, G. VanKoten

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

The new diarylplatinum complex Cis-[Pt(PEt(3))(2){C6H3(CH(2)NMe(2))(2)-3,5}(2)] 1, containing four free amine coordination sites, undergoes directed lithiation with Bu(t)Li and subsequent transmetallation with [PtCl2(SEt(2))(2)] to give a triplatinum species 3 which reductively eliminates the diplatinum complex[ClPt{2,6-(Me(2)NCH(2))(2)C6H2-C6H2(CH(2)NMe(2))(2)-2,6}PtCl] 4.
Original languageEnglish
Pages (from-to)253-255
Number of pages3
JournalChemical Communications
Volume1996
Publication statusPublished - 1996

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