Synthesis of Gold–Silver Luminescent Honeycomb Aggregates by Both Solvent-Based and Solvent-Free Methods

M. Carmen Blanco, Jessica Camara, M. Concepcion Gimeno, Antonio Laguna, Stuart James, Cristina Lagunas-Castedo, M. Dolores Villacampa

Research output: Contribution to journalArticlepeer-review

37 Citations (Scopus)

Abstract

Heterometallic clusters with strong luminescence have been synthesized (see picture: Au(CCPh)2 yellow-red, Ag2 blue, O red) from the metalloligand unit [Au(CCPh)PPh3] (yellow/red bars) by using both standard solvent-based and solvent-free reactions. The aggregates are stabilized only by acetylide–metal or metal–metal interactions, and their nuclearity is controlled through the addition of different donor ligands.
Original languageEnglish
Pages (from-to)9777-9779
Number of pages3
JournalAngewandte Chemie International Edition
Volume51
Issue number39
Early online date24 Aug 2012
DOIs
Publication statusPublished - 24 Sep 2012

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