Synthesis of isomeric polyacetylenes based on natural hydroxy matricaria esters

S. Garrais; J. Turkington; William Goldring

doi:10.1016/j.tet.2009.07.082

Synthesis of isomeric polyacetylenes based on natural hydroxy matricaria esters

S. Garrais, J. Turkington, William Goldring

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

The construction of a library of natural and related polyacetylenes using a convergent synthetic strategy based on a palladium mediated cross-coupling reaction is described. The systematic synthetic study led to all possible alkene isomers of the hydroxy matricaria esters 29-32, and the corresponding tiglates 1-4. The synthesis of many of these compounds is described for the first time.

Original language	English
Pages (from-to)	8418-8427
Number of pages	10
Journal	Tetrahedron
Volume	65
Issue number	40
DOIs	https://doi.org/10.1016/j.tet.2009.07.082
Publication status	Published - 03 Oct 2009

ASJC Scopus subject areas

Biochemistry
Organic Chemistry
Drug Discovery

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10.1016/j.tet.2009.07.082

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title = "Synthesis of isomeric polyacetylenes based on natural hydroxy matricaria esters",

abstract = "The construction of a library of natural and related polyacetylenes using a convergent synthetic strategy based on a palladium mediated cross-coupling reaction is described. The systematic synthetic study led to all possible alkene isomers of the hydroxy matricaria esters 29-32, and the corresponding tiglates 1-4. The synthesis of many of these compounds is described for the first time.",

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AU - Garrais, S.

AU - Turkington, J.

AU - Goldring, William

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N2 - The construction of a library of natural and related polyacetylenes using a convergent synthetic strategy based on a palladium mediated cross-coupling reaction is described. The systematic synthetic study led to all possible alkene isomers of the hydroxy matricaria esters 29-32, and the corresponding tiglates 1-4. The synthesis of many of these compounds is described for the first time.

AB - The construction of a library of natural and related polyacetylenes using a convergent synthetic strategy based on a palladium mediated cross-coupling reaction is described. The systematic synthetic study led to all possible alkene isomers of the hydroxy matricaria esters 29-32, and the corresponding tiglates 1-4. The synthesis of many of these compounds is described for the first time.

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DO - 10.1016/j.tet.2009.07.082

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EP - 8427

JO - Tetrahedron

JF - Tetrahedron

IS - 40

ER -

Synthesis of isomeric polyacetylenes based on natural hydroxy matricaria esters

Abstract

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