Tandem enzyme-catalysed oxidations of alkyl phenyl sulfides and alkyl benzenes: enantiocomplementary routes to chiral phenols.

Derek Boyd; Narain Das Sharma; Vera Ljubez; Breige E. Byrne; Steven Shepherd; C Allen; Leonid Kulakov; Mike Larkin; H. Dalton

doi:10.1039/b205903g

Tandem enzyme-catalysed oxidations of alkyl phenyl sulfides and alkyl benzenes: enantiocomplementary routes to chiral phenols.

Derek Boyd
, Narain Das Sharma
, Vera Ljubez
, Breige E. Byrne
, Steven Shepherd
, C Allen
, Leonid Kulakov
, Mike Larkin
, H. Dalton

Research output: Contribution to journal › Article › peer-review

33 Citations (Scopus)

Abstract

Dioxygenase-catalysed trioxygenation of alkyl phenyl sulfides and alkyl benzenes yields enantiopure cis-dihydrodiol sulfoxides and triols respectively; naphthalene cis-dihydrodiol dehydrogenase-catalysed aromatisation of these diastereoisomers gives enantiopure catechols of either configuration.

Original language	English
Pages (from-to)	1914-1915
Number of pages	2
Journal	Chemical Communications
Volume	17
Issue number	17
DOIs	https://doi.org/10.1039/b205903g
Publication status	Published - 2002

ASJC Scopus subject areas

General Chemistry

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10.1039/b205903g

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title = "Tandem enzyme-catalysed oxidations of alkyl phenyl sulfides and alkyl benzenes: enantiocomplementary routes to chiral phenols.",

abstract = "Dioxygenase-catalysed trioxygenation of alkyl phenyl sulfides and alkyl benzenes yields enantiopure cis-dihydrodiol sulfoxides and triols respectively; naphthalene cis-dihydrodiol dehydrogenase-catalysed aromatisation of these diastereoisomers gives enantiopure catechols of either configuration.",

author = "Derek Boyd and \{Das Sharma\}, Narain and Vera Ljubez and Byrne, \{Breige E.\} and Steven Shepherd and C Allen and Leonid Kulakov and Mike Larkin and H. Dalton",

year = "2002",

doi = "10.1039/b205903g",

language = "English",

volume = "17",

pages = "1914--1915",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - Tandem enzyme-catalysed oxidations of alkyl phenyl sulfides and alkyl benzenes: enantiocomplementary routes to chiral phenols.

AU - Boyd, Derek

AU - Das Sharma, Narain

AU - Ljubez, Vera

AU - Byrne, Breige E.

AU - Shepherd, Steven

AU - Allen, C

AU - Kulakov, Leonid

AU - Larkin, Mike

AU - Dalton, H.

PY - 2002

Y1 - 2002

N2 - Dioxygenase-catalysed trioxygenation of alkyl phenyl sulfides and alkyl benzenes yields enantiopure cis-dihydrodiol sulfoxides and triols respectively; naphthalene cis-dihydrodiol dehydrogenase-catalysed aromatisation of these diastereoisomers gives enantiopure catechols of either configuration.

AB - Dioxygenase-catalysed trioxygenation of alkyl phenyl sulfides and alkyl benzenes yields enantiopure cis-dihydrodiol sulfoxides and triols respectively; naphthalene cis-dihydrodiol dehydrogenase-catalysed aromatisation of these diastereoisomers gives enantiopure catechols of either configuration.

UR - https://www.scopus.com/pages/publications/0036966847

U2 - 10.1039/b205903g

DO - 10.1039/b205903g

M3 - Article

SN - 1359-7345

VL - 17

SP - 1914

EP - 1915

JO - Chemical Communications

JF - Chemical Communications

IS - 17

ER -

Tandem enzyme-catalysed oxidations of alkyl phenyl sulfides and alkyl benzenes: enantiocomplementary routes to chiral phenols.

Abstract

ASJC Scopus subject areas

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