Tethering of Pentamethylcyclopentadienyl and N-Heterocycle Stabilized Carbene Ligands by Intramolecular 1,4-Addition to a Polyfluorophenyl Substituent

Hayden P. Thomas; Andrew C. Marr; Patrick J. Morgan; Graham C. Saunders

doi:10.1021/acs.organomet.8b00164

Tethering of Pentamethylcyclopentadienyl and N-Heterocycle Stabilized Carbene Ligands by Intramolecular 1,4-Addition to a Polyfluorophenyl Substituent

Hayden P. Thomas, Andrew C. Marr, Patrick J. Morgan, Graham C. Saunders

Research output: Contribution to journal › Article

3 Citations (Scopus)

119 Downloads (Pure)

Abstract

On treatment with silver(I) oxide the complex [Cp*RhCl2(κC-MeNC3H2NCH2C6F5)] undergoes 1,4-addition of rhodium and methylene to the polyfluoroaryl ring, which loses aromaticity, affording [(η5,κ2C-C5Me4CH2C6F5CH2NC3H2NMe)RhCl].

Original language	English
Number of pages	3
Journal	Organometallics
Early online date	02 May 2018
DOIs	https://doi.org/10.1021/acs.organomet.8b00164
Publication status	Early online date - 02 May 2018

Access to Document

10.1021/acs.organomet.8b00164Licence: Unspecified

Tethering of Pentamethylcyclopentadienyl and N-Heterocycle Stabilized Carbene Ligands by Intramolecular 1,4-Addition to a Polyfluorophenyl Substituent
© 2018 American Chemical Society. This work is made available online in accordance with the publisher’s policies. Please refer to any applicable terms of use of the publisher.
Accepted author manuscript, 293 KBLicence: Unspecified

Fingerprint Dive into the research topics of 'Tethering of Pentamethylcyclopentadienyl and N-Heterocycle Stabilized Carbene Ligands by Intramolecular 1,4-Addition to a Polyfluorophenyl Substituent'. Together they form a unique fingerprint.

Cite this

Thomas, H. P., Marr, A. C., Morgan, P. J., & Saunders, G. C. (2018). Tethering of Pentamethylcyclopentadienyl and N-Heterocycle Stabilized Carbene Ligands by Intramolecular 1,4-Addition to a Polyfluorophenyl Substituent. Organometallics. https://doi.org/10.1021/acs.organomet.8b00164

@article{1560ccd9c0fc4e61afaba4d36d42f71f,

title = "Tethering of Pentamethylcyclopentadienyl and N-Heterocycle Stabilized Carbene Ligands by Intramolecular 1,4-Addition to a Polyfluorophenyl Substituent",

abstract = "On treatment with silver(I) oxide the complex [Cp*RhCl2(κC-MeNC3H2NCH2C6F5)] undergoes 1,4-addition of rhodium and methylene to the polyfluoroaryl ring, which loses aromaticity, affording [(η5,κ2C-C5Me4CH2C6F5CH2NC3H2NMe)RhCl].",

author = "Thomas, {Hayden P.} and Marr, {Andrew C.} and Morgan, {Patrick J.} and Saunders, {Graham C.}",

year = "2018",

month = may,

day = "2",

doi = "10.1021/acs.organomet.8b00164",

language = "English",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

}

TY - JOUR

T1 - Tethering of Pentamethylcyclopentadienyl and N-Heterocycle Stabilized Carbene Ligands by Intramolecular 1,4-Addition to a Polyfluorophenyl Substituent

AU - Thomas, Hayden P.

AU - Marr, Andrew C.

AU - Morgan, Patrick J.

AU - Saunders, Graham C.

PY - 2018/5/2

Y1 - 2018/5/2

N2 - On treatment with silver(I) oxide the complex [Cp*RhCl2(κC-MeNC3H2NCH2C6F5)] undergoes 1,4-addition of rhodium and methylene to the polyfluoroaryl ring, which loses aromaticity, affording [(η5,κ2C-C5Me4CH2C6F5CH2NC3H2NMe)RhCl].

AB - On treatment with silver(I) oxide the complex [Cp*RhCl2(κC-MeNC3H2NCH2C6F5)] undergoes 1,4-addition of rhodium and methylene to the polyfluoroaryl ring, which loses aromaticity, affording [(η5,κ2C-C5Me4CH2C6F5CH2NC3H2NMe)RhCl].

U2 - 10.1021/acs.organomet.8b00164

DO - 10.1021/acs.organomet.8b00164

M3 - Article

JO - Organometallics

JF - Organometallics

SN - 0276-7333

ER -