Tethering of Pentamethylcyclopentadienyl and N-Heterocycle Stabilized Carbene Ligands by Intramolecular 1,4-Addition to a Polyfluorophenyl Substituent

Hayden P. Thomas, Andrew C. Marr, Patrick J. Morgan, Graham C. Saunders

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Abstract

On treatment with silver(I) oxide the complex [Cp*RhCl2(κC-MeNC3H2NCH2C6F5)] undergoes 1,4-addition of rhodium and methylene to the polyfluoroaryl ring, which loses aromaticity, affording [(η5,κ2C-C5Me4CH2C6F5CH2NC3H2NMe)RhCl].
Original languageEnglish
Number of pages3
JournalOrganometallics
Early online date02 May 2018
DOIs
Publication statusEarly online date - 02 May 2018

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