Tethering of Pentamethylcyclopentadienyl and N-Heterocycle Stabilized Carbene Ligands by Intramolecular 1,4-Addition to a Polyfluorophenyl Substituent

Hayden P. Thomas; Andrew C. Marr; Patrick J. Morgan; Graham C. Saunders

doi:10.1021/acs.organomet.8b00164

Tethering of Pentamethylcyclopentadienyl and N-Heterocycle Stabilized Carbene Ligands by Intramolecular 1,4-Addition to a Polyfluorophenyl Substituent

Hayden P. Thomas, Andrew C. Marr, Patrick J. Morgan, Graham C. Saunders

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Abstract

On treatment with silver(I) oxide the complex [Cp*RhCl2(κC-MeNC3H2NCH2C6F5)] undergoes 1,4-addition of rhodium and methylene to the polyfluoroaryl ring, which loses aromaticity, affording [(η5,κ2C-C5Me4CH2C6F5CH2NC3H2NMe)RhCl].

Original language	English
Number of pages	3
Journal	Organometallics
Early online date	02 May 2018
DOIs	https://doi.org/10.1021/acs.organomet.8b00164
Publication status	Early online date - 02 May 2018

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Tethering of Pentamethylcyclopentadienyl and N-Heterocycle Stabilized Carbene Ligands by Intramolecular 1,4-Addition to a Polyfluorophenyl Substituent
© 2018 American Chemical Society. This work is made available online in accordance with the publisher’s policies. Please refer to any applicable terms of use of the publisher.
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@article{1560ccd9c0fc4e61afaba4d36d42f71f,

title = "Tethering of Pentamethylcyclopentadienyl and N-Heterocycle Stabilized Carbene Ligands by Intramolecular 1,4-Addition to a Polyfluorophenyl Substituent",

abstract = "On treatment with silver(I) oxide the complex [Cp*RhCl2(κC-MeNC3H2NCH2C6F5)] undergoes 1,4-addition of rhodium and methylene to the polyfluoroaryl ring, which loses aromaticity, affording [(η5,κ2C-C5Me4CH2C6F5CH2NC3H2NMe)RhCl].",

author = "Thomas, \{Hayden P.\} and Marr, \{Andrew C.\} and Morgan, \{Patrick J.\} and Saunders, \{Graham C.\}",

year = "2018",

month = may,

day = "2",

doi = "10.1021/acs.organomet.8b00164",

language = "English",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Tethering of Pentamethylcyclopentadienyl and N-Heterocycle Stabilized Carbene Ligands by Intramolecular 1,4-Addition to a Polyfluorophenyl Substituent

AU - Thomas, Hayden P.

AU - Marr, Andrew C.

AU - Morgan, Patrick J.

AU - Saunders, Graham C.

PY - 2018/5/2

Y1 - 2018/5/2

N2 - On treatment with silver(I) oxide the complex [Cp*RhCl2(κC-MeNC3H2NCH2C6F5)] undergoes 1,4-addition of rhodium and methylene to the polyfluoroaryl ring, which loses aromaticity, affording [(η5,κ2C-C5Me4CH2C6F5CH2NC3H2NMe)RhCl].

AB - On treatment with silver(I) oxide the complex [Cp*RhCl2(κC-MeNC3H2NCH2C6F5)] undergoes 1,4-addition of rhodium and methylene to the polyfluoroaryl ring, which loses aromaticity, affording [(η5,κ2C-C5Me4CH2C6F5CH2NC3H2NMe)RhCl].

U2 - 10.1021/acs.organomet.8b00164

DO - 10.1021/acs.organomet.8b00164

M3 - Article

SN - 0276-7333

JO - Organometallics

JF - Organometallics

ER -

Tethering of Pentamethylcyclopentadienyl and N-Heterocycle Stabilized Carbene Ligands by Intramolecular 1,4-Addition to a Polyfluorophenyl Substituent

Abstract

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