The first structural characterization of a [2.2]PHANEPHOS - Transition-metal complex: Structure of rac-[Pd(4,12-bis(diphenylphosphino)[2.2]paracyclophane)Cl-2]

P.W. Dyer, P.J. Dyson, Stuart James, C.M. Martin, P. Suman

Research output: Contribution to journalArticlepeer-review

25 Citations (Scopus)

Abstract

The solid-state structure of the [2.2]PHANEPHOS-transition-metal complex rac-[Pd(4,12-bis(diphenylphosphino)[2.2]paracyclophane)Cl-2] has been established by single-crystal X-ray diffraction. The P-Pd-P bite angle is ideally suited to catalytic processes such as carbon-carbon cross-coupling reactions, which involve reductive elimination as the rate-determining step.
Original languageEnglish
Pages (from-to)4344-4346
Number of pages3
JournalOrganometallics
Volume17
Publication statusPublished - 1998

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