The first structural characterization of a [2.2]PHANEPHOS - Transition-metal complex: Structure of rac-[Pd(4,12-bis(diphenylphosphino)[2.2]paracyclophane)Cl-2]

P.W. Dyer; P.J. Dyson; Stuart James; C.M. Martin; P. Suman

The first structural characterization of a [2.2]PHANEPHOS - Transition-metal complex: Structure of rac-[Pd(4,12-bis(diphenylphosphino)[2.2]paracyclophane)Cl-2]

P.W. Dyer, P.J. Dyson, Stuart James, C.M. Martin, P. Suman

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

The solid-state structure of the [2.2]PHANEPHOS-transition-metal complex rac-[Pd(4,12-bis(diphenylphosphino)[2.2]paracyclophane)Cl-2] has been established by single-crystal X-ray diffraction. The P-Pd-P bite angle is ideally suited to catalytic processes such as carbon-carbon cross-coupling reactions, which involve reductive elimination as the rate-determining step.

Original language	English
Pages (from-to)	4344-4346
Number of pages	3
Journal	Organometallics
Volume	17
Publication status	Published - 1998

Cite this

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title = "The first structural characterization of a [2.2]PHANEPHOS - Transition-metal complex: Structure of rac-[Pd(4,12-bis(diphenylphosphino)[2.2]paracyclophane)Cl-2]",

abstract = "The solid-state structure of the [2.2]PHANEPHOS-transition-metal complex rac-[Pd(4,12-bis(diphenylphosphino)[2.2]paracyclophane)Cl-2] has been established by single-crystal X-ray diffraction. The P-Pd-P bite angle is ideally suited to catalytic processes such as carbon-carbon cross-coupling reactions, which involve reductive elimination as the rate-determining step.",

author = "P.W. Dyer and P.J. Dyson and Stuart James and C.M. Martin and P. Suman",

year = "1998",

language = "English",

volume = "17",

pages = "4344--4346",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

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T1 - The first structural characterization of a [2.2]PHANEPHOS - Transition-metal complex: Structure of rac-[Pd(4,12-bis(diphenylphosphino)[2.2]paracyclophane)Cl-2]

AU - Dyer, P.W.

AU - Dyson, P.J.

AU - James, Stuart

AU - Martin, C.M.

AU - Suman, P.

PY - 1998

Y1 - 1998

N2 - The solid-state structure of the [2.2]PHANEPHOS-transition-metal complex rac-[Pd(4,12-bis(diphenylphosphino)[2.2]paracyclophane)Cl-2] has been established by single-crystal X-ray diffraction. The P-Pd-P bite angle is ideally suited to catalytic processes such as carbon-carbon cross-coupling reactions, which involve reductive elimination as the rate-determining step.

AB - The solid-state structure of the [2.2]PHANEPHOS-transition-metal complex rac-[Pd(4,12-bis(diphenylphosphino)[2.2]paracyclophane)Cl-2] has been established by single-crystal X-ray diffraction. The P-Pd-P bite angle is ideally suited to catalytic processes such as carbon-carbon cross-coupling reactions, which involve reductive elimination as the rate-determining step.

M3 - Article

VL - 17

SP - 4344

EP - 4346

JO - Organometallics

JF - Organometallics

SN - 0276-7333

ER -

The first structural characterization of a [2.2]PHANEPHOS - Transition-metal complex: Structure of rac-[Pd(4,12-bis(diphenylphosphino)[2.2]paracyclophane)Cl-2]

Abstract

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