The fragmentation dynamics of CS2 2+

Thomas A. Field*, John H D Eland

*Corresponding author for this work

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

The fragmentation of CS2 2+ has been investigated by recording photoelectron photoion coincidence (PEPICO) and photoelectron photoion photoion coincidence (PEPIPICO) spectra with energy analysis of the photoelectron, excited by HeIIα (40.8 eV) radiation. From these spectra mean dication energies can be determined; it is found that the mean energy of metastable CS2 2+ ions is 27.6±0.4 eV, that the mean energy of states which fragment to give CS++S+ is 32.7±0.4 eV and that the mean internal energy of the fragments CS++S+ is ~2 eV.

Original languageEnglish
Pages (from-to)144-150
Number of pages7
JournalChemical Physics Letters
Volume303
Issue number1-2
Publication statusPublished - 02 Apr 1999
Externally publishedYes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Atomic and Molecular Physics, and Optics

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    Field, T. A., & Eland, J. H. D. (1999). The fragmentation dynamics of CS2 2+. Chemical Physics Letters, 303(1-2), 144-150.