Abstract
New methods of synthesis and reactions of formylphosphonate have been investigated. Attempts to deprotect the corresponding diethyl acetal with Ti-IV halides led instead to the formation of halo(ethoxy)methylphosphonates which undergo substitution reactions with a wide range of nucleophiles. The products of reactions of formylphosphonate with bifunctional nucleophiles are determined in most cases by Baldwin's Roles, while the imines derived from formylphosphonate undergo Diels-Alder reactions only in those cases which carry a strongly electron-withdrawing N-substituent.
| Original language | English |
|---|---|
| Pages (from-to) | 385-388 |
| Number of pages | 4 |
| Journal | Phosphorus sulfur and silicon and the related elements |
| Volume | 146 |
| Publication status | Published - 1999 |
| Event | XIVth International Conference on Phosphorus Chemistry (XIVth-ICPC) - CINCINNATI, United States Duration: 12 Jul 1998 → 17 Jul 1998 |
Keywords
- hetero Diels-Alder
- formylphosphonate