Thermotropic Ruthenium(II)-Containing Metallomesogens Based on Substituted 1,10-Phenanthroline Ligands

T. Cardinaels, J. Ramaekers, K. Driesen, Peter Nockemann, K. Van Hecke, L. Van Meervelt, B. Goderis, K. Binnemans

Research output: Contribution to journalArticle

33 Citations (Scopus)

Abstract

Imidazo[4,5-f]-1,10-phenanthroline and pyrazino[2,3-f]-1,10-phenanthroline substituted with long alkyl chains are versatile ligands for the design of metallomesogens because of the ease of ligand substitution. Whereas the ligands and the corresponding rhenium(I) complexes were not liquid-crystalline, mesomorphism was observed for the corresponding ionic ruthenium(II) complexes with chloride, hexafluorophosphate, and bistriflimide counterions. The mesophases were identified as smectic A phases by high-temperature small-angle X-ray scattering (SAXS) using synchrotron radiation. The transition temperatures depend on the anion, the highest temperatures being observed for the chloride salts and the lowest for the bistriflimide salts. The ruthenium(II) complexes are examples of luminescent ionic liquid crystals.
Original languageEnglish
Pages (from-to)2490-2499
Number of pages10
JournalInorganic Chemistry
Volume48
Issue number6
DOIs
Publication statusPublished - 16 Mar 2009

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry

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