Total Synthesis of (+)-Azinothricin and (+)-Kettapeptin

Karl J Hale; Soraya Manaviazar; J.H. George; M.A. Walters; S.M. Dalby

doi:10.1021/ol802817t

Total Synthesis of (+)-Azinothricin and (+)-Kettapeptin

Karl J Hale, Soraya Manaviazar, J.H. George, M.A. Walters, S.M. Dalby

Research output: Contribution to journal › Article › peer-review

39 Citations (Scopus)

Abstract

Asymmetric total syntheses of (+)-azinothricin and (+)-kettapeptin have been completed through a common new pathway that exploits a highly chemoselective coupling reaction between the fully elaborated cyclodepsipeptide 5 and the glycal activated esters 3 and 4 at the final stages of both respective syntheses.

Original language	English
Pages (from-to)	733-736
Number of pages	4
Journal	Organic Letters
Volume	11
Issue number	3
Early online date	06 Jan 2009
DOIs	https://doi.org/10.1021/ol802817t
Publication status	Published - 05 Feb 2009

ASJC Scopus subject areas

Organic Chemistry
Physical and Theoretical Chemistry
Biochemistry

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title = "Total Synthesis of (+)-Azinothricin and (+)-Kettapeptin",

abstract = "Asymmetric total syntheses of (+)-azinothricin and (+)-kettapeptin have been completed through a common new pathway that exploits a highly chemoselective coupling reaction between the fully elaborated cyclodepsipeptide 5 and the glycal activated esters 3 and 4 at the final stages of both respective syntheses.",

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T1 - Total Synthesis of (+)-Azinothricin and (+)-Kettapeptin

AU - Hale, Karl J

AU - Manaviazar, Soraya

AU - George, J.H.

AU - Walters, M.A.

AU - Dalby, S.M.

PY - 2009/2/5

Y1 - 2009/2/5

N2 - Asymmetric total syntheses of (+)-azinothricin and (+)-kettapeptin have been completed through a common new pathway that exploits a highly chemoselective coupling reaction between the fully elaborated cyclodepsipeptide 5 and the glycal activated esters 3 and 4 at the final stages of both respective syntheses.

AB - Asymmetric total syntheses of (+)-azinothricin and (+)-kettapeptin have been completed through a common new pathway that exploits a highly chemoselective coupling reaction between the fully elaborated cyclodepsipeptide 5 and the glycal activated esters 3 and 4 at the final stages of both respective syntheses.

U2 - 10.1021/ol802817t

DO - 10.1021/ol802817t

M3 - Article

SN - 1523-7060

VL - 11

SP - 733

EP - 736

JO - Organic Letters

JF - Organic Letters

IS - 3

ER -

Total Synthesis of (+)-Azinothricin and (+)-Kettapeptin

Abstract

ASJC Scopus subject areas

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