Tunable thermomorphism and applications of ionic liquid analogues of Girard's reagents

Marijana Blesic; H. Q. Nimal Gunaratne; Johan Jacquemin; Peter Nockemann; Sonia Olejarz; Kenneth R. Seddon; Christopher R. Strauss

doi:10.1039/c4gc01159g

Tunable thermomorphism and applications of ionic liquid analogues of Girard's reagents

Marijana Blesic^*, H. Q. Nimal Gunaratne, Johan Jacquemin, Peter Nockemann, Sonia Olejarz, Kenneth R. Seddon, Christopher R. Strauss

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

A series of ionic liquids based on Girard's reagents was synthesised. Their tunable thermomorphic behaviour with water was demonstrated, and slight modifications in the cationic structure led to drastic changes in their water miscibility. Their phase behaviour, involving monophasic–biphasic transitions, drove a number of practical applications, including scavenging water-soluble dyes and the extraction of metals from water.

Original language	English
Pages (from-to)	4115-4121
Number of pages	7
Journal	Green Chemistry
Volume	16
Issue number	9
DOIs	https://doi.org/10.1039/c4gc01159g
Publication status	Published - Sept 2014

Keywords

TRANSITION-METAL-COMPLEXES
AQUEOUS-SOLUTIONS
MUTUAL SOLUBILITIES
EXTRACTION PROCESS
PLUS WATER
REMOVAL
SEPARATION
BEHAVIOR
SYSTEMS
DYES

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10.1039/c4gc01159g

Marijana Blesic
- m.blesicqub.acuk
Person: Academic
Nimal Gunaratne
- n.gunaratnequb.acuk
- School of Chemistry and Chemical Engineering - Honorary Senior Lecturer
Person: Honorary

Cite this

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title = "Tunable thermomorphism and applications of ionic liquid analogues of Girard's reagents",

abstract = "A series of ionic liquids based on Girard's reagents was synthesised. Their tunable thermomorphic behaviour with water was demonstrated, and slight modifications in the cationic structure led to drastic changes in their water miscibility. Their phase behaviour, involving monophasic–biphasic transitions, drove a number of practical applications, including scavenging water-soluble dyes and the extraction of metals from water. ",

keywords = "TRANSITION-METAL-COMPLEXES, AQUEOUS-SOLUTIONS, MUTUAL SOLUBILITIES, EXTRACTION PROCESS, PLUS WATER, REMOVAL, SEPARATION, BEHAVIOR, SYSTEMS, DYES",

author = "Marijana Blesic and Gunaratne, {H. Q. Nimal} and Johan Jacquemin and Peter Nockemann and Sonia Olejarz and Seddon, {Kenneth R.} and Strauss, {Christopher R.}",

year = "2014",

month = sep,

doi = "10.1039/c4gc01159g",

language = "English",

volume = "16",

pages = "4115--4121",

journal = "Green Chemistry",

issn = "1463-9262",

publisher = "Royal Society of Chemistry",

number = "9",

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T1 - Tunable thermomorphism and applications of ionic liquid analogues of Girard's reagents

AU - Blesic, Marijana

AU - Gunaratne, H. Q. Nimal

AU - Jacquemin, Johan

AU - Nockemann, Peter

AU - Olejarz, Sonia

AU - Seddon, Kenneth R.

AU - Strauss, Christopher R.

PY - 2014/9

Y1 - 2014/9

N2 - A series of ionic liquids based on Girard's reagents was synthesised. Their tunable thermomorphic behaviour with water was demonstrated, and slight modifications in the cationic structure led to drastic changes in their water miscibility. Their phase behaviour, involving monophasic–biphasic transitions, drove a number of practical applications, including scavenging water-soluble dyes and the extraction of metals from water.

AB - A series of ionic liquids based on Girard's reagents was synthesised. Their tunable thermomorphic behaviour with water was demonstrated, and slight modifications in the cationic structure led to drastic changes in their water miscibility. Their phase behaviour, involving monophasic–biphasic transitions, drove a number of practical applications, including scavenging water-soluble dyes and the extraction of metals from water.

KW - TRANSITION-METAL-COMPLEXES

KW - AQUEOUS-SOLUTIONS

KW - MUTUAL SOLUBILITIES

KW - EXTRACTION PROCESS

KW - PLUS WATER

KW - REMOVAL

KW - SEPARATION

KW - BEHAVIOR

KW - SYSTEMS

KW - DYES

U2 - 10.1039/c4gc01159g

DO - 10.1039/c4gc01159g

M3 - Article

SN - 1463-9262

VL - 16

SP - 4115

EP - 4121

JO - Green Chemistry

JF - Green Chemistry

IS - 9

ER -

Tunable thermomorphism and applications of ionic liquid analogues of Girard's reagents

Abstract

Keywords

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Marijana Blesic

Nimal Gunaratne

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