Two mercuric ammoniates: [Hg(NH3)(2)][HgCl3](2) and [Hg(NH3)(4)](ClO4)(2)

Peter Nockemann; G. Meyer

Two mercuric ammoniates: [Hg(NH3)(2)][HgCl3](2) and [Hg(NH3)(4)](ClO4)(2)

Peter Nockemann
, G. Meyer

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

[Hg(NH3)(2)][HgCl3](2) (1) is obtained by saturating an equimolar solution of HgCl2 and NH4Cl with Hg(NH2)Cl at 75 degreesC. 1 crystallizes in the orthorhombic space group Pmna with a = 591.9(1) pm, b = 800.3(1) pm, c = 1243.3(4) pm, Z = 2. The structure consists of linear cations [Hg(NH3)(2)](2+) and T-shaped anions [HgCl3](-). The coordination sphere of mercury is

Original language	English
Pages (from-to)	123-128
Number of pages	6
Journal	ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
Volume	629
Issue number	1
Publication status	Published - 2003

ASJC Scopus subject areas

Inorganic Chemistry

Cite this

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abstract = "[Hg(NH3)(2)][HgCl3](2) (1) is obtained by saturating an equimolar solution of HgCl2 and NH4Cl with Hg(NH2)Cl at 75 degreesC. 1 crystallizes in the orthorhombic space group Pmna with a = 591.9(1) pm, b = 800.3(1) pm, c = 1243.3(4) pm, Z = 2. The structure consists of linear cations [Hg(NH3)(2)](2+) and T-shaped anions [HgCl3](-). The coordination sphere of mercury is",

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AU - Meyer, G.

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N2 - [Hg(NH3)(2)][HgCl3](2) (1) is obtained by saturating an equimolar solution of HgCl2 and NH4Cl with Hg(NH2)Cl at 75 degreesC. 1 crystallizes in the orthorhombic space group Pmna with a = 591.9(1) pm, b = 800.3(1) pm, c = 1243.3(4) pm, Z = 2. The structure consists of linear cations [Hg(NH3)(2)](2+) and T-shaped anions [HgCl3](-). The coordination sphere of mercury is

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UR - https://www.scopus.com/pages/publications/0037259426

M3 - Article

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JO - ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

JF - ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

IS - 1

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Two mercuric ammoniates: [Hg(NH3)(2)][HgCl3](2) and [Hg(NH3)(4)](ClO4)(2)

Abstract

ASJC Scopus subject areas

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