Type 3 porous liquids based on non-ionic liquid phases – a broad and tailorable platform of selective, fluid gas sorbents

John Cahir; Min Ying Tsang; Beibei Lai; David Hughes; M. Ashraf  Alam; Johan Jacquemin; David Rooney; Stuart L. James

doi:10.1039/C9SC05770F

Type 3 porous liquids based on non-ionic liquid phases – a broad and tailorable platform of selective, fluid gas sorbents

John Cahir, Min Ying Tsang, Beibei Lai, David Hughes, M. Ashraf Alam, Johan Jacquemin, David Rooney, Stuart L. James

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

99 Citations (Scopus)

194 Downloads (Pure)

Abstract

We describe a series of Type 3 porous liquids, denoted “T3PLs”, based on a wide range of microporous solids including MOFs, zeolites and a porous organic polymer (PAF-1). These solids are dispersed in various non-ionic liquid phases (including silicone oils, triglyceride oils, and polyethylene glycols) which have a range of structures and properties, and that are in many cases sterically excluded from the pores of the solids. Several stable dispersions with high gas uptakes are obtained. We show how these dispersions can be tailored toward important gas separation processes (CO2/CH4, C2H4/C2H6) and applications that require biocompatibility.

Original language	English
Number of pages	7
Journal	Chemical Science
DOIs	https://doi.org/10.1039/C9SC05770F
Publication status	Published - 09 Jan 2020

Access to Document

10.1039/C9SC05770FLicence: CC BY

Type 3 porous liquids based on non-ionic liquid phases – a broad and tailorable platform of selective, fluid gas sorbents
Copyright 2020 the authors. This is an open access article published under a Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited.
Final published version, 1.42 MBLicence: CC BY

The synthesis, design and study of new Type 3 porous liquids
Cahir, J. (Author), James, S. (Supervisor) & Jacquemin, J. (Supervisor), Jul 2021
Student thesis: Doctoral Thesis › Doctor of Philosophy

Cite this

@article{429934f85f274d97a6c631976935897d,

title = "Type 3 porous liquids based on non-ionic liquid phases – a broad and tailorable platform of selective, fluid gas sorbents",

abstract = "We describe a series of Type 3 porous liquids, denoted “T3PLs”, based on a wide range of microporous solids including MOFs, zeolites and a porous organic polymer (PAF-1). These solids are dispersed in various non-ionic liquid phases (including silicone oils, triglyceride oils, and polyethylene glycols) which have a range of structures and properties, and that are in many cases sterically excluded from the pores of the solids. Several stable dispersions with high gas uptakes are obtained. We show how these dispersions can be tailored toward important gas separation processes (CO2/CH4, C2H4/C2H6) and applications that require biocompatibility.",

author = "John Cahir and Tsang, {Min Ying} and Beibei Lai and David Hughes and Alam, {M. Ashraf} and Johan Jacquemin and David Rooney and James, {Stuart L.}",

year = "2020",

month = jan,

day = "9",

doi = "10.1039/C9SC05770F",

language = "English",

journal = "Chemical Science",

issn = "2041-6520",

publisher = "Royal Society of Chemistry",

}

TY - JOUR

T1 - Type 3 porous liquids based on non-ionic liquid phases – a broad and tailorable platform of selective, fluid gas sorbents

AU - Cahir, John

AU - Tsang, Min Ying

AU - Lai, Beibei

AU - Hughes, David

AU - Alam, M. Ashraf

AU - Jacquemin, Johan

AU - Rooney, David

AU - James, Stuart L.

PY - 2020/1/9

Y1 - 2020/1/9

N2 - We describe a series of Type 3 porous liquids, denoted “T3PLs”, based on a wide range of microporous solids including MOFs, zeolites and a porous organic polymer (PAF-1). These solids are dispersed in various non-ionic liquid phases (including silicone oils, triglyceride oils, and polyethylene glycols) which have a range of structures and properties, and that are in many cases sterically excluded from the pores of the solids. Several stable dispersions with high gas uptakes are obtained. We show how these dispersions can be tailored toward important gas separation processes (CO2/CH4, C2H4/C2H6) and applications that require biocompatibility.

AB - We describe a series of Type 3 porous liquids, denoted “T3PLs”, based on a wide range of microporous solids including MOFs, zeolites and a porous organic polymer (PAF-1). These solids are dispersed in various non-ionic liquid phases (including silicone oils, triglyceride oils, and polyethylene glycols) which have a range of structures and properties, and that are in many cases sterically excluded from the pores of the solids. Several stable dispersions with high gas uptakes are obtained. We show how these dispersions can be tailored toward important gas separation processes (CO2/CH4, C2H4/C2H6) and applications that require biocompatibility.

U2 - 10.1039/C9SC05770F

DO - 10.1039/C9SC05770F

M3 - Article

SN - 2041-6520

JO - Chemical Science

JF - Chemical Science

ER -

Type 3 porous liquids based on non-ionic liquid phases – a broad and tailorable platform of selective, fluid gas sorbents

Abstract

Access to Document

Fingerprint

Student theses

The synthesis, design and study of new Type 3 porous liquids

Cite this