Abstract
The temperature curves of the ultimate high-frequency electroconductivity of water and acetonitrile were analyzed. The temperature curves of specific electroconductivity of aqueous 0.1 M sodium chloride solution and acetonitrile 0.1 M 1-butyl-3-methylimidazol trifluoromethane sulfonate were compared. The electroconductivity activation energy of solutions was found coinciding with the ultimate high-frequency electroconductivity activation energy of solvents within the experimental error. The specific electroconductivity of solutions was shown to increase at higher temperature in direct proportion to the ultimate high-frequency electroconductivity of solvents.
| Original language | English |
|---|---|
| Pages (from-to) | 922-924 |
| Number of pages | 3 |
| Journal | Russian Journal of Electrochemistry |
| Volume | 45 |
| Issue number | 8 |
| DOIs | |
| Publication status | Published - Aug 2009 |
Keywords
- Acetonitrile 1-butyl-3-methylimidazol trifluoromethane sulfonate solution
- Aqueous sodium chloride solution
- Dielectric solvent characteristics
- Specific electroconductivity
- Ultimate high-frequency electroconductivity
ASJC Scopus subject areas
- Electrochemistry