Viscosity of binary mixtures of cycloalkane with cycloalkane, alkane and aromatic hydrocarbon at 303.15 K

S.L. Oswal, M.M. Maisuria, Ramesh Gardas

Research output: Contribution to journalArticle

20 Citations (Scopus)

Abstract

The viscosity ? for eighteen binary mixtures cyclopentane + cyclohexane and + cyclooctane; cyclohexane + cycloheptane, + cyclooctane, + methylcyclohexane, + n-hexane, + n-heptane, + n-octane, + i-octane, + benzene, + toluene, + ethylbenzene, + p-xylene, and + propylbenzene; methylcyclohexane + n-hexane, + i-octane, and + benzene; and cyclooctane + benzene have been reported at 303.15 K over the entire range of composition. The viscosity deviations ?? and excess Gibbs energy of activation ?G*E of viscous flow based on Eyring's theory have been calculated. The effects of molecular sizes and shapes of the component molecules and of interaction energy in the mixture have been discussed. The viscosity data have been correlated with the equations of Grunberg and Nissan, Hind, McLaughlin and Ubbelohde, Tamura and Kurata, Katti and Chaudhri, McAllister, Heric and Brewer, and of Auslaender.
Original languageEnglish
Pages (from-to)199-215
Number of pages17
JournalJournal of Molecular Liquids
Volume108 (1-3)
Issue number1-3
DOIs
Publication statusPublished - Nov 2003

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Atomic and Molecular Physics, and Optics

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