Visible and Near-Infrared Emission by Samarium(III)-Containing Ionic Liquid Mixtures

K. Lunstroot, Peter Nockemann, K. Van Hecke, L. Van Meervelt, C. Gorller-Walrand, K. Binnemans, K. Driesen

Research output: Contribution to journalArticlepeer-review

110 Citations (Scopus)

Abstract

Highly luminescent anionic samarium(III) beta-diketonate and dipicolinate complexes were dissolved in the imidazolium ionic liquid 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, [C(6)mim][Tf2N]. The solubility of the complexes in the ionic liquid was ensured by a careful choice of the countercation of the samarium(III) complex. The samarium(III) complexes that were considered are [C(6)mim][SM(tta)(4)], where tta is 2-thenoyltrifluoroacetonate; [C(6)mim][Sm(nta)(4)], where nta is 2-naphthoyltrifluoroacetonate; [C(6)mim][Sm(hfa)(4)], where hfa is hexafluoroacetylacetonate; and [choline](3)-[Sm(dpa)(3)], where dpa is pyridine-2,6-dicarboxylate (dipicolinate) and [choline](+) is (2-hydroxyethyl)trimethyl ammonium. The crystal structures of the tetrakis samarium(III) P-diketonate complexes revealed a distorted square antiprismatic coordination for the samarium(III) ion in all three cases. Luminescence spectra were recorded for the samarium(III) complexes dissolved in the imidazolium ionic liquid as well as in a conventional solvent, that is, acetonitrile or water for the beta-diketonate and dipicolinate complexes, respectively. These experiments demonstrate that [C(6)mim][Tf2N] is a suitable spectroscopic solvent for studying samarium(III) luminescence. High-luminescence quantum yields were observed for the samarium(III) beta-diketonate complexes in solution.
Original languageEnglish
Pages (from-to)3018-3026
Number of pages9
JournalInorganic Chemistry
Volume48
Issue number7
DOIs
Publication statusPublished - 2009

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry

Fingerprint

Dive into the research topics of 'Visible and Near-Infrared Emission by Samarium(III)-Containing Ionic Liquid Mixtures'. Together they form a unique fingerprint.

Cite this