Wholly Biobased, Highly Stretchable, Hydrophobic, and Self-healing Thermoplastic Elastomer

Yeyen Nurhamiyah, Amalina Amir, Marie Finnegan, Efrosyni Themistou, Mohan Edirisinghe, Biqiong Chen

Research output: Contribution to journalArticlepeer-review

7 Citations (Scopus)
238 Downloads (Pure)


Renewable polymers with excellent stretchability and self-healing ability are interesting for a wide range of applications. A novel type of wholly biobased, self-healing, polyamide-based thermoplastic elastomer was synthesized using a fatty dimer acid and a fatty dimer amine, both containing multiple alkyl chains, through facile one-pot condensation polymerization under different polymerization times. The resulting elastomer shows superior stretchability (up to 2286%), high toughness, and excellent shape recovery after being stretched to different strains. This elastomer also displays high room-temperature autonomous self-healing efficiency after fracture and zero water uptake during water immersion. The highly entangled main chain, the multiple dangling chains, the abundant reversible physical bonds, the intermolecular diffusion, and the low ratio of amide to methylene group within the elastomer are responsible for these extraordinary properties. The polymerization time influences the properties of the elastomer. The use of the optimal self-healing thermoplastic elastomer in anticorrosion coating, piezoresistive sensing, and highly stretchable fibers is also demonstrated. The elastomer coating prevents stainless-steel products from corrosion in a salty environment due to its superhydrophobicity. The elastomer serves as a robust flexible substrate for creating self-healing piezoresistive sensors with excellent repeatability and self-healing efficiency. The elastomer fiber yarn can be stretched to 950% of its original length confirming its outstanding stretchability.

Original languageEnglish
Pages (from-to)6720-6730
Number of pages11
JournalACS Applied Materials and Interfaces
Issue number5
Early online date26 Jan 2021
Publication statusPublished - 10 Feb 2021


  • General Materials Science


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