A comparison of choline:urea and choline:oxalic acid deep eutectic solvents at 338 K

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      1:2 choline chloride:urea and 1:1 choline chloride:oxalic acid deep eutectic solvents are compared at 338 K using liquid-phase neutron diffraction with H/D isotopic substitution to obtain differential neutron scattering cross sections and fitting of models to the experimental data using Empirical Potential Structure Refinement. In comparison to the previously reported study of choline chloride:urea at 303 K, we observed significant weakening and lengthening of choline–OH· · · Cl and choline–OH· · · hydrogen-bond acceptor correlations.

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      DOI

      Original languageEnglish
      Article number193823
      Number of pages10
      JournalJournal of Chemical Physics
      Journal publication date12 Feb 2018
      Volume148
      DOIs
      StatePublished - 12 Feb 2018

      ID: 141090583