Giant Resistive Switching in Mixed Phase BiFeO3 via phase population control

    Research output: Contribution to journalArticle


    View graph of relations

    Highly-strained coherent interfaces, between Rhombohedral-like (R) and Tetragonal-like (T) phases in BiFeO3 thin films, often show enhanced electrical conductivity in comparison to non-interfacial regions. In principle, changing the population and distribution of these interfaces should therefore allow different resistance states to be created. However, doing this controllably has been challenging to date. Here, we show that local thin film phase microstructures (and hence R-T interface densities) can be changed in a thermodynamically predictable way (predictions made using atomistic simulations) by applying different combinations of mechanical stress and electric field. We use both pressure and electric field to reversibly generate metastable changes in microstructure that result in very large changes of resistance of up to 10^8 %, comparable to those seen in Tunnelling Electro-Resistance (TER) devices.


    • Giant resistive switching in mixed phase BiFeO3via phase population control

      Rights statement: Copyright 2018 the authors. This is an open access article published under a Creative Commons Attribution License (, which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited.

      Final published version, 3 MB, PDF-document


    Original languageEnglish
    Pages (from-to)1-9
    Journal publication date07 Oct 2018
    Issue number37
    Early online date03 Sep 2018
    Publication statusPublished - 07 Oct 2018

      Research areas

    • phase competition, resistive switching, localized stress, ferroelectrics

    ID: 156861943